Researchers have also shown that they can make basic solar
cells, light-emitting devices, touch screens, photodetectors and mode-lock ultra-fast lasers from the graphene. However, there are, of course, drawbacks:
graphene's "external quantum efficiency" is low – it absorbs less
than 3% of the light falling on it. Furthermore, useful electrical current can
only be extracted from graphene-based devices that have electrical contacts
with an optimized "asymmetry" – something that has proven difficult
to achieve.
Now, researchers at the University of Cambridge and the
University of Manchester may have solved both these problems by pairing up
graphene with plasmonic nano structures. These are metal devices that enhance
local electromagnetic fields in a material by coupling incoming light with
electrons on the surface of the metal. The nano structures are fabricated on top
of graphene samples to concentrate the electromagnetic field in the region of
the material where light is converted to electrical current, so as to
dramatically increase the generated photovoltage.
The team, which includes Manchester's Andre Geim and Kostya
Novoselov, winners of the 2010 Nobel Prize for Physics for their discovery of
graphene, started out by preparing samples of graphene using the now-famous
"sticky tape" method. This involves mechanically shaving off single
layers of graphene from a block of graphite. The researchers then made
two-terminal electronic devices from the material by forming contacts made of
titanium and gold on the graphene using electron-beam lithography. Next,
various plasmonic nano structures were assembled close to the contacts.
The new devices have an external quantum efficiency of
almost 50%, the highest value to date for graphene. This boosts the
light-harvesting capacity of graphene by more than an order of magnitude
compared to its non-contacted counterpart, without sacrificing it's speed.
Furthermore, the problem of creating contacts with the
desired asymmetry is addressed through the use of titanium and gold in the
device.
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